Which of the following factors would not affect rates of reaction?
- A. Temperature
- B. Surface area
- C. Pressure
- D. Time
Correct Answer: D
Rationale: Time would not directly affect rates of reaction. The rate of a chemical reaction is determined by factors that affect the frequency of successful collisions between reactant molecules, leading to a reaction. Temperature, surface area, and pressure can influence reaction rates by impacting the kinetic energy of molecules, the exposed surface for collisions, and the concentration of reactants, respectively. However, time, in the context of this question, does not alter the rate of reaction but may affect the extent of the reaction or the amount of product formed over time.
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Which of the following is not an allotrope of carbon?
- A. Diamond
- B. Graphite
- C. Fluorine
- D. Buckminsterfullerene
Correct Answer: C
Rationale: The correct answer is C: Fluorine. Allotropes of carbon are different forms of the same element. Diamonds, graphite, and buckminsterfullerene are all allotropes of carbon. However, fluorine is a separate chemical element and not an allotrope of carbon. Therefore, fluorine does not belong to the group of carbon allotropes.
Which of these types of intermolecular force is the strongest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct Answer: D
Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.
On what concept is Kelvin based?
- A. Freezing point
- B. Absolute zero
- C. Boiling point
- D. Evaporation point
Correct Answer: B
Rationale: The correct answer is B: Absolute zero. Kelvin is based on the concept of absolute zero, which is the point where molecular movement ceases entirely. This temperature scale starts at absolute zero (0K), where theoretically no molecular movement occurs. Choices A, C, and D are incorrect because Kelvin is not based on the freezing point, boiling point, or evaporation point, but rather on the absolute absence of molecular motion.
What is the charge of an alpha particle?
- A. -1
- B. +1
- C. +2
- D. No charge
Correct Answer: C
Rationale: An alpha particle consists of two protons and two neutrons, resulting in a total charge of +2 due to the presence of two positively charged protons. Therefore, the correct answer is C, indicating a charge of +2. Choices A, B, and D are incorrect because an alpha particle is positively charged due to the two protons it contains, resulting in a charge of +2.
Which ion would you expect to dominate in water solutions of bases?
- A. MgClâ‚‚
- B. 2HCl
- C. Hâº
- D. OHâ»
Correct Answer: D
Rationale: In water solutions of bases, the dominant ion would be OH⻠(hydroxide ion). Bases release OH⻠ions when dissolved in water, increasing the concentration of hydroxide ions and leading to a higher pH. This is in contrast to acids, which release H⺠ions. Therefore, in water solutions of bases, the presence of OH⻠ions signifies the basic nature of the solution. Choices A, B, and C are incorrect because MgCl₂ is a salt, 2HCl is a compound consisting of two hydrogen ions and one chloride ion, and H⺠represents a hydrogen ion typically associated with acids, not bases.