Which of the following is a chief difference between evaporation and boiling?
Correct Answer: C
Rationale: The chief difference between evaporation and boiling is that evaporation can happen below a liquid's boiling point, while boiling only occurs at the liquid's boiling point. Evaporation is the process of a liquid turning into a gas at any temperature, while boiling specifically refers to the rapid vaporization that occurs when a liquid reaches its boiling point. Choice A is incorrect because liquids evaporate throughout the liquid, not just at the surface. Choice B is incorrect as evaporating substances change from liquid to gas, while boiling substances change from liquid to gas. Choice C is incorrect as boiling is not a man-made phenomenon; in fact, it is a natural process based on temperature changes. Choice D is incorrect because evaporation can happen naturally and is not limited to man-made processes.