Nokea
Which of the following lists four factors that affect rates of reaction?
- A. Barometric pressure, particle size, concentration, and the presence of a facilitator
- B. Temperature, particle size, concentration, and the presence of a catalyst
- C. Temperature, container material, elevation, and the presence of instability
- D. Volatility, particle size, concentration, and the presence of a catalyst
Correct Answer: B
Rationale: The correct answer is B. The factors that influence rates of reaction are temperature, particle size, concentration, and the presence of a catalyst. Temperature affects the speed of molecules, particle size impacts the available surface area for reactions, concentration influences the collision frequency between reactant molecules, and catalysts accelerate reactions by providing an alternative pathway with lower activation energy. Choices A, C, and D are incorrect as they either include irrelevant factors that do not affect reaction rates (barometric pressure, container material, elevation, and volatility) or lack important factors that do influence reaction rates (like a catalyst).
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The volume of a gas is directly proportional to its absolute temperature at constant pressure. This is a statement of:
- A. Combined Gas Law
- B. Boyle's Law
- C. Charles' Law
- D. The Ideal Gas Law
Correct Answer: C
Rationale: Charles' Law states that the volume of a gas is directly proportional to its absolute temperature at constant pressure. This means that as the temperature of a gas increases, its volume also increases proportionally, and vice versa. This relationship between temperature and volume is a key feature of Charles' Law. The Combined Gas Law involves the relationships between pressure, volume, and temperature of a gas. Boyle's Law describes the inverse relationship between the pressure and volume of a gas at constant temperature. The Ideal Gas Law combines Boyle's Law, Charles' Law, and Avogadro's Law into a single expression. Therefore, the correct answer is Charles' Law, as it specifically describes the direct relationship between the temperature and volume of a gas.
Which law is expressed by the equation: Ptot = Pa + Pb, where P represents pressure, Ptot is the total pressure, and Pa and Pb are component pressures?
- A. Henry's law
- B. Dalton's law
- C. Boyle's law
- D. Gay-Lussac's law
Correct Answer: B
Rationale: The correct answer is B, Dalton's law. Dalton's law states that in a mixture of non-reacting gases, the total pressure is equal to the sum of the partial pressures of the individual gases. The equation Ptot = Pa + Pb represents Dalton's law, where Ptot is the total pressure, and Pa and Pb are the component pressures. Choice A, Henry's law, deals with the solubility of gases in liquids. Choice C, Boyle's law, describes the inverse relationship between the pressure and volume of a gas at constant temperature. Choice D, Gay-Lussac's law, states that the pressure of a gas is directly proportional to its absolute temperature when volume is constant.
One factor that affects rates of reaction is concentration. Which of these statements about concentration is/are correct?
- A. A higher concentration of reactants causes more effective collisions per unit time, leading to an increased reaction rate
- B. A lower concentration of reactants causes fewer effective collisions per unit time, leading to a decreased reaction rate
- C. A higher concentration of reactants causes more effective collisions per unit time, leading to a decreased reaction rate
- D. A higher concentration of reactants causes fewer effective collisions per unit time, leading to an increased reaction rate
Correct Answer: A
Rationale: A higher concentration of reactants causes more effective collisions per unit time, leading to an increased reaction rate. This is because a higher concentration means there are more reactant molecules in a given volume, increasing the likelihood of collisions between them. With more collisions occurring, there is a greater chance of successful collisions leading to the formation of products, hence increasing the reaction rate. Choice B is incorrect as a lower concentration decreases the number of collisions, reducing the reaction rate. Choice C is incorrect as a higher concentration increases collision frequency, which typically results in a higher reaction rate. Choice D is incorrect as a higher concentration usually leads to more collisions, thus increasing the reaction rate.
What type of bonds involve an especially strong dipole-dipole force between molecules and are responsible for the unique properties of water and pin DNA into its characteristic shape?
- A. Oxygen links
- B. Hydrogen bonds
- C. Dipolar bonds
- D. N/A
Correct Answer: B
Rationale: Hydrogen bonds involve an especially strong dipole-dipole force between molecules. These bonds are responsible for the unique properties of water, such as its high surface tension and ability to form droplets. Additionally, hydrogen bonds help hold DNA strands together in its characteristic double helix shape, playing a crucial role in DNA structure and stability. Choice A, 'Oxygen links,' is incorrect as it does not accurately describe the type of bonds involved. Choice C, 'Dipolar bonds,' is also incorrect as it is a generalized term and does not specifically refer to the bonds described in the question. Choice D, 'N/A,' is irrelevant and does not provide an answer to the question.
Which, if any, of these statements about solubility is correct?
- A. The solubility of a substance is defined as its concentration in a saturated solution
- B. Substances with solubilities much less than 1 g/100 mL of solvent are generally considered insoluble
- C. A saturated solution is one that cannot dissolve any more solute
- D. All of these statements are correct
Correct Answer: D
Rationale: A. The solubility of a substance is indeed defined as the concentration of a solute that can be dissolved in a solvent to form a saturated solution at a specific temperature and pressure. B. Substances with solubilities much less than 1 g/100 mL of solvent are generally considered insoluble because they do not dissolve in significant amounts in the solvent. C. A saturated solution is one that cannot dissolve any more solute as it has reached its maximum capacity at a specific temperature and pressure. Therefore, all the statements provided are correct, making option D the correct answer.