Which of these intermolecular forces might represent attraction between atoms of a noble gas?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct Answer: B
Rationale: Noble gases are non-polar molecules without a permanent dipole moment. The only intermolecular force applicable to noble gases is the London dispersion force, also known as Van der Waals forces. This force is a temporary attractive force resulting from the formation of temporary dipoles in non-polar molecules. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding involve significant dipoles or hydrogen atoms bonded to electronegative atoms, which do not apply to noble gases.
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Which substance shows a decrease in solubility in water with an increase in temperature?
- A. NaCl
- B. O
- C. KI
- D. CaCl
Correct Answer: C
Rationale: Potassium iodide (KI) shows a decrease in solubility in water with an increase in temperature. This is due to the dissolution of KI in water being an endothermic process. When the temperature rises, the equilibrium shifts toward the solid state, leading to a decrease in solubility. Therefore, as the temperature increases, KI becomes less soluble in water.
Choice A (NaCl) and Choice D (CaCl) do not exhibit a decrease in solubility with an increase in temperature. NaCl and CaCl are generally more soluble in water at higher temperatures. Choice B (Oxygen) is a gas and not typically considered in solubility discussions involving solids or liquids dissolving in water.
What are the products of combustion of a hydrocarbon in excess oxygen?
- A. Carbon dioxide and water
- B. Naphthalene
- C. Chlorine and bromine
- D. Carbonium ions
Correct Answer: A
Rationale: The correct answer is A: Carbon dioxide and water. During the combustion of a hydrocarbon in excess oxygen, the hydrocarbon reacts to produce carbon dioxide and water vapor as the final products. This reaction is known as complete combustion, where the hydrocarbon combines with oxygen to form carbon dioxide and water. Choices B, C, and D are incorrect because naphthalene is a specific hydrocarbon compound, chlorine and bromine are not typically formed during the combustion of hydrocarbons in excess oxygen, and carbonium ions are not the products of this reaction.
The molar mass of some gases is as follows: carbon monoxide-28.01 g/mol; helium-4.00 g/mol; nitrogen-28.01 g/mol; and oxygen-32.00 g/mol. Which would you expect to diffuse most rapidly?
- A. Carbon monoxide
- B. Helium
- C. Nitrogen
- D. Oxygen
Correct Answer: B
Rationale: The rate of diffusion is inversely proportional to the molar mass of the gas. Helium has the lowest molar mass among the given gases, making it the lightest and fastest gas to diffuse. Therefore, helium would be expected to diffuse most rapidly compared to carbon monoxide, nitrogen, and oxygen. Carbon monoxide, nitrogen, and oxygen have higher molar masses than helium, so they would diffuse more slowly. Therefore, the correct answer is helium.
Which of the following compounds is ionic?
- A. NaCl
- B. Hâ‚‚O
- C. HCl
- D. NH₃
Correct Answer: A
Rationale: The correct answer is NaCl (sodium chloride). Ionic compounds are formed by the transfer of electrons between a metal and a nonmetal. In NaCl, sodium (Na) is a metal, and chlorine (Cl) is a nonmetal. Sodium donates an electron to chlorine, leading to the formation of the ionic bond between them. This results in the formation of an ionic compound, where positively charged sodium ions are attracted to negatively charged chloride ions, creating a crystal lattice structure. Choices B, C, and D are not ionic compounds. H₂O (water) is a covalent compound formed by the sharing of electrons between two nonmetals (oxygen and hydrogen). HCl (hydrogen chloride) and NH₃ (ammonia) are also covalent compounds involving nonmetals sharing electrons, not transferring them.
How many electrons are in a neutral atom of neon?
- A. 9
- B. 10
- C. 11
- D. 12
Correct Answer: B
Rationale: The atomic number of neon is 10, which represents the number of protons in its nucleus. In a neutral atom, the number of electrons is equal to the number of protons to maintain electrical neutrality. Therefore, a neutral atom of neon contains 10 electrons, matching the 10 protons within the nucleus. Choice A (9 electrons) is incorrect as it doesn't correspond to the atomic number of neon. Choices C (11 electrons) and D (12 electrons) are also incorrect as they do not align with the correct atomic number of neon.