Which property of a substance does not change with a change in temperature?
- A. Mass
- B. Volume
- C. Phase
- D. Solubility
Correct Answer: A
Rationale: Mass is an intrinsic property of a substance that remains constant regardless of temperature changes. It is a measure of the amount of matter in an object, and this quantity does not vary with temperature or the environment in which the substance is located. The conservation of mass in chemistry dictates that mass is neither created nor destroyed, making it independent of temperature variations.\nVolume, on the other hand, changes with temperature due to thermal expansion or contraction. Phase can change with temperature, leading to transitions between solid, liquid, and gas states. Solubility is affected by temperature changes as it influences the ability of a substance to dissolve in a solvent.
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When a gas is compressed isothermally, we can say that:
- A. The gas performs work on the surroundings, and its internal energy increases.
- B. The gas performs work on the surroundings, and its internal energy decreases.
- C. The surroundings perform work on the gas, and its internal energy increases.
- D. The surroundings perform work on the gas, and its internal energy decreases.
Correct Answer: D
Rationale: When a gas is compressed isothermally, the surroundings perform work on the gas. In this process, since the temperature remains constant (isothermal), the internal energy of the gas does not change. Therefore, the correct answer is that the surroundings perform work on the gas, and its internal energy decreases. Choices A, B, and C are incorrect because they incorrectly describe the direction of work and the change in internal energy during an isothermal compression.
Enthalpy (H) is a thermodynamic property defined as the sum of a system's internal energy (U) and the product of its pressure (P) and volume (V). The relationship between these is:
- A. H = U + PV
- B. H = U - PV
- C. H = U / PV
- D. H = PV / U
Correct Answer: A
Rationale: Enthalpy (H) is defined as H = U + PV, where U represents internal energy, P is pressure, and V is volume. Enthalpy includes both the internal energy of a system and the energy required to create space for the system against an external pressure. Therefore, the correct relationship between enthalpy, internal energy, pressure, and volume is H = U + PV. Choice B is incorrect as subtracting PV would not account for the work done against pressure. Choice C is incorrect as dividing U by PV doesn't represent the definition of enthalpy. Choice D is incorrect as dividing PV by U is not the correct relationship based on the definition of enthalpy.
Marilyn is driving to a wedding. She drives 4 miles south before realizing that she left the gift at home. She makes a U-turn, returns home to pick up the gift, and sets out again driving south. This time, she drives 1 mile out of her way to pick up a friend. From there, they continue 5 miles more to the wedding. Which of these statements is true about Marilyn's trip?
- A. The displacement of her trip is 6 miles, and the distance traveled is 6 miles.
- B. The displacement of her trip is 14 miles, and the distance traveled is 14 miles.
- C. The displacement of her trip is 8 miles, and the distance traveled is 14 miles.
- D. The displacement of her trip is 6 miles, and the distance traveled is 14 miles.
Correct Answer: C
Rationale: Marilyn's displacement is calculated based on her final position relative to the starting point. She drives 1 mile to pick up her friend, then 5 miles more to the wedding, totaling 6 miles after returning to her home. So, the correct displacement is 8 miles south from her starting point (4 miles to the gift + 4 miles return + 1 mile to the friend + 5 miles to the wedding). The total distance traveled is 14 miles (adding all the distances). Choice A is incorrect because it miscalculates the displacement. Choice B is incorrect as it overestimates both the displacement and distance traveled. Choice D is incorrect as it underestimates the displacement.
What is the kinetic energy of a 500-kg wagon moving at 10 m/s?
- A. 50 J
- B. 250 J
- C. 2.5 10^4 J
- D. 5.0 10^5 J
Correct Answer: C
Rationale: The formula for calculating kinetic energy is KE = 0.5 mass velocity². Given the mass of the wagon is 500 kg and the velocity is 10 m/s, we can substitute these values into the formula: KE = 0.5 500 kg (10 m/s)² = 0.5 500 kg 100 m²/s² = 25,000 J or 2.5 10â´ J. Therefore, the kinetic energy of the 500-kg wagon moving at 10 m/s is 2.5 10â´ J. Choice A (50 J) is incorrect because it is too low; Choice B (250 J) is incorrect as it does not match the correct calculation; Choice D (5.0 10^5 J) is incorrect as it is too high. The correct answer is C (2.5 10^4 J).
The efficiency (η) of a heat engine is defined as the ratio of the net work done (Wnet) by the engine to the heat input (Qh) from the hot reservoir. The relationship is expressed as:
- A. η = Wnet / Qh
- B. η = Qh / Wnet
- C. η = Wnet x Qh
- D. η = (Wnet + Qh) / 2
Correct Answer: A
Rationale: The correct formula for efficiency (η) of a heat engine is η = Wnet / Qh. Efficiency is defined as the ratio of the net work done by the engine (Wnet) to the heat input from the hot reservoir (Qh). This formula shows how effectively the engine converts heat into useful work, making choice A the correct answer. Choices B, C, and D present incorrect relationships between efficiency, net work done, and heat input, leading to their incorrectness.